ABSTRACT

Densities of the binary systems containing an isomer of chlorobutane (1-chlorobutane, 2- chlorobutane, 2-methyl-1-chloropropane, or 2-methyl-2-chloropropane) and butyl ethyl ether have been measured in the temperature range 283.15 K - 313.15 K. Moreover, isothermal vapour-liquid equilibria have also been determined at three temperatures (T = 288.15 K, 298.15 K, and 308.15 K). Excess properties have been obtained from the experimental data and correlated. Finally, the VTPR model has been used to predict densities and vapour-liquid equilibria of the binary systems studied.

Compounds

#	Formula	Name
1	C4H9Cl	1-chlorobutane
2	C4H9Cl	2-chlorobutane
3	C4H9Cl	1-chloro-2-methylpropane
4	C4H9Cl	2-chloro-2-methylpropane
5	C6H14O	butyl ethyl ether

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	Ebulliometric method (Recirculating still)	3
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	7
POMD	2	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	Ebulliometric method (Recirculating still)	3
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	7
POMD	3	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	Ebulliometric method (Recirculating still)	3
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	9
POMD	4	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	Ebulliometric method (Recirculating still)	3
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	7
POMD	5	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	Ebulliometric method (Recirculating still)	3
POMD	5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	7
POMD	1 5	Vapor or sublimation pressure, kPa ; Liquid	Mole fraction - 1; Liquid Temperature, K; Liquid		Liquid Gas	Ebulliometric method (Recirculating still)	39
POMD	1 5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	91
POMD	1 5	Mole fraction - 1 ; Gas	Mole fraction - 1; Liquid Temperature, K; Liquid		Gas Liquid	Density calibration data	39
POMD	2 5	Vapor or sublimation pressure, kPa ; Liquid	Mole fraction - 2; Liquid Temperature, K; Liquid		Liquid Gas	Ebulliometric method (Recirculating still)	33
POMD	2 5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 2; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	91
POMD	2 5	Mole fraction - 2 ; Gas	Mole fraction - 2; Liquid Temperature, K; Liquid		Gas Liquid	Density calibration data	33
POMD	3 5	Vapor or sublimation pressure, kPa ; Liquid	Mole fraction - 3; Liquid Temperature, K; Liquid		Liquid Gas	Ebulliometric method (Recirculating still)	33
POMD	3 5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	91
POMD	3 5	Mole fraction - 3 ; Gas	Mole fraction - 3; Liquid Temperature, K; Liquid		Gas Liquid	Density calibration data	33
POMD	4 5	Vapor or sublimation pressure, kPa ; Liquid	Mole fraction - 4; Liquid Temperature, K; Liquid		Liquid Gas	Ebulliometric method (Recirculating still)	33
POMD	4 5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 4; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	91
POMD	4 5	Mole fraction - 4 ; Gas	Mole fraction - 4; Liquid Temperature, K; Liquid		Gas Liquid	Density calibration data	33

Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Experimental and predicted properties of the binary mixtures containing an isomeric chlorobutane and butyl ethyl ether

Montano, d.[diego], Gascon, I.[Ignacio], Schmid, B.[Bastian], Gmehling, J.[Jurgen], Lafuente, C.[Carlos]

ABSTRACT