Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Studies on intermolecular interactions in nitrobenzene + alkoxyethanol binary mixtures by relative permittivity measurements at T = (293.15, 298.15, 303.15, 308.15 and 313.15) K

Kinart, C. M.[Cezary M.], Cwiklinska, A. [Aneta], Bald, A.[Adam], Kinart, Z.[Zdzislaw]
J. Chem. Thermodyn. 2012, 50, 37-42
ABSTRACT
Relative permittivities, at T = (293.15, 298.15, 303.15, 308.15 and 313.15) K, in the binary mixtures of nitrobenzene with 2-methoxyethanol, 2-ethoxyethanol, 2-propoxyethanol and 2-butoxyethanol have been measured as a function of composition. From the experimental data the deviations in the relative permittivity at T = (293.15, 298.15, 303.15, 308.15 and 313.15) K and the excesses of temperature coefficient of relative permittivity at T = 298.15 K from a mole fraction average have been calculated. The results are discussed in terms of intermolecular interactions and structure of studied binary mixtures.
Compounds
# Formula Name
1 C6H5NO2 nitrobenzene
2 C3H8O2 2-methoxyethan-1-ol
3 C4H10O2 2-ethoxyethan-1-ol
4 C5H12O2 2-propoxyethanol
5 C6H14O2 2-butoxyethan-1-ol
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Relative permittivity at various frequencies ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Frequency, MHz; Liquid
  • Liquid
  • OH-301 Stainless Steel Cell
  • 5
  • POMD
  • 2
  • Relative permittivity at various frequencies ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Frequency, MHz; Liquid
  • Liquid
  • OH-301
  • 6
  • POMD
  • 3
  • Relative permittivity at various frequencies ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Frequency, MHz; Liquid
  • Liquid
  • OH-301
  • 5
  • POMD
  • 4
  • Relative permittivity at various frequencies ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Frequency, MHz; Liquid
  • Liquid
  • OH-301
  • 5
  • POMD
  • 5
  • Relative permittivity at various frequencies ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Frequency, MHz; Liquid
  • Liquid
  • OH-301
  • 5
  • POMD
  • 1
  • 2
  • Relative permittivity at various frequencies ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Frequency, MHz; Liquid
  • Liquid
  • OH-301
  • 75
  • POMD
  • 1
  • 3
  • Relative permittivity at various frequencies ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Frequency, MHz; Liquid
  • Liquid
  • OH-301
  • 75
  • POMD
  • 1
  • 4
  • Relative permittivity at various frequencies ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Frequency, MHz; Liquid
  • Liquid
  • OH-301
  • 75
  • POMD
  • 1
  • 5
  • Relative permittivity at various frequencies ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Frequency, MHz; Liquid
  • Liquid
  • OH-301
  • 75