Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Determination of the diffusion coefficient of CO2 in the ionic liquid EMIM NTf2 using online FTIR measurements

Kortenbruck, K., Pohrer, B., Schluecker, E., Friedel, F., Ivanovic-Burmazovic, I.
J. Chem. Thermodyn. 2012, 47, 76-80
ABSTRACT
Physical data concerning the absorption kinetics like the diffusion coefficients are important values for designing an economically working gas separation processes. Considering ionic liquids, which emerged in recent years as interesting alternative solvent media for versatile industrial purposes, usually only solubility data for gases are available if at all. Therefore in order to gain additional information such as diffusion coefficients of gases in ionic liquids, we established an efficient and easily assembled set-up based on time-resolved FTIR measurements. Applying this methodology, the diffusion coefficient of carbon dioxide in 1-ethyl-3-methyl-imidizolium bis[(trifluoromethyl)sulfonyl]amide (EMIM NTf2) was determined at a temperature of 303 K.
Compounds
# Formula Name
1 C8H11F6N3O4S2 1-ethyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide
2 CO2 carbon dioxide
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 1
  • Binary diffusion coefficient, m2/s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 2; Liquid
  • Liquid
  • Time resolved FTIR
  • 6