Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Experimental density and viscosity measurements of di(2ethylhexyl)sebacate at high pressure

Paredes, X.[Xavier], Fandino, O.[Olivia], Pensado, A. S.[Alfonso S.], Comunas, M. J. P.[Maria J.P.], Fernandez, J.[Josefa]
J. Chem. Thermodyn. 2012, 44, 1, 38-43
ABSTRACT
Experimental densities and dynamic viscosities of di(2-ethylhexyl)sebacate (DEHS) are the object of study in this work. DEHS could be a useful industrial reference fluid for moderately high viscosity at high pressures as it is often used as a pressure transmitting fluid. At atmospheric pressure the density and viscosity measurements have been performed in a rotational SVM 3000 Stabinger viscometer from (273.15 to 373.15) K, whereas from (0.1 to 60) MPa and from (298.15 to 398.15) K an automated Anton Paar DMA HPM vibrating-tube densimeter, and a high-pressure rolling-ball viscometer were used. Several Vogel-Fulcher-Tammann type equations were used to fit the experimental values of viscosity to the pressure and temperature. The measured viscosity data have been used together with previous data found in the literature to establish a correlation of the viscosity surface eta(T, p) of DEHS, covering a temperature range from (273 to 491) K and pressure up to 1.1 GPa. This correlation could be used in industrial equipment like viscometers and other devices that operate at high pressures. Our viscosity data have also been fitted as a function of temperature and volume to the thermodynamic scaling model of Roland et al. [C.M. Roland, S. Bair, R. Casalini, J. Chem. Phys. 125 (2006) 124508].
Compounds
# Formula Name
1 C26H50O4 bis(2-ethylhexyl) decanedioate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Concentric cylinders viscometry
  • 20
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 20
  • POMD
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Falling or rolling sphere viscometry
  • 66
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 53