Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

The partial molar heat capacity, expansion, isentropic, and isothermal compressions of thymidine in aqueous solution at T = 298.15 K

Hedwig, G. R.[Gavin R.], Jameson, G. J., Hoiland, H.[Harald]
J. Chem. Thermodyn. 2011, 43, 12, 1936-1941
ABSTRACT
Solution densities have been determined for aqueous solutions of thymidine at T = (288.15, 298.15, 303.15, and 313.15) K. The partial molar volumes at infinite dilution obtained from the density data were used to derive the partial molar isobaric expansion at infinite dilution for thymidine at T = 298.15 K. The partial molar heat capacity at infinite dilution for thymidine at T = 298.15 K has also been determined. Sound speeds have been measured for aqueous solutions of thymidine at T = 298.15 K. The partial molar isentropic compression at infinite dilution and the partial molar isothermal compression at infinite dilution have been derived from the sound speed data. These results for thymidine are criritcally evaluated with those avaialble from the literature.
Compounds
# Formula Name
1 C10H14N2O5 thymidine
2 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • Molar heat capacity at constant pressure, J/K/mol ; Liquid
  • Molality, mol/kg - 1; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Flow calorimetry
  • 9
  • POMD
  • 1
  • 2
  • Speed of sound, m/s ; Liquid
  • Molality, mol/kg - 1; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • unknown
  • 10
  • POMD
  • 1
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 36