Name: ThermoML Representation of Published Experimental Data from Journal of Chemical Thermodynamics (0021-9614, Elsevier)
Creator: Thermodynamics Research Center
License: https://www.nist.gov/open/license

ABSTRACT

Vapor pressures and the molar enthalpies of vaporization of the linear aliphatic alkanediamines H2N-(CH2)n NH2 with n = (3 to 12) have been determined using the transpiration method. A linear correlation of enthalpies of vaporization (at T = 298.15 K) of the alkanediamines with the number n and with the Kovat s indices has been found, proving the internal consistency of the measured data.

Compounds

#	Formula	Name
1	C3H10N2	1,3-propanediamine
2	C4H12N2	1,4-butanediamine
3	C5H14N2	1,5-diaminopentane
4	C6H16N2	1,6-hexanediamine
5	C7H18N2	1,7-diaminoheptane
6	C8H20N2	1,8-diaminooctane
7	C9H22N2	1,9-diaminononane
8	C10H24N2	1,10-diaminodecane
9	C11H26N2	1,11-Diaminoundecane
10	C12H28N2	1,12-dodecanediamine

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Phase	Method	#Points
POMD	1	Molar enthalpy of transition or fusion, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Derived from vapor pressure measurement	13
POMD	1	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	13
POMD	2	Molar enthalpy of transition or fusion, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Derived from vapor pressure measurement	22
POMD	2	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	22
POMD	3	Molar enthalpy of transition or fusion, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Derived from vapor pressure measurement	42
POMD	3	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	42
POMD	4	Molar enthalpy of transition or fusion, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Derived from vapor pressure measurement	30
POMD	4	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	30
POMD	5	Molar enthalpy of transition or fusion, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Derived from vapor pressure measurement	24
POMD	5	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	24
POMD	6	Molar enthalpy of transition or fusion, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Derived from vapor pressure measurement	21
POMD	6	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	21
POMD	7	Molar enthalpy of transition or fusion, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Derived from vapor pressure measurement	38
POMD	7	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	38
POMD	8	Molar enthalpy of transition or fusion, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Derived from vapor pressure measurement	20
POMD	8	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	20
POMD	9	Molar enthalpy of transition or fusion, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Derived from vapor pressure measurement	13
POMD	9	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	13
POMD	10	Molar enthalpy of transition or fusion, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	Derived from vapor pressure measurement	14
POMD	10	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	14

Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Vapor pressure and enthalpy of vaporization of linear aliphatic alkanediamines

Pozdeev, V. A.[Vasiliy A.], Verevkin, S. P.[Sergey P.]

ABSTRACT