Name: ThermoML Representation of Published Experimental Data from Journal of Chemical Thermodynamics (0021-9614, Elsevier)
Creator: Thermodynamics Research Center
License: https://www.nist.gov/open/license

ABSTRACT

Vapor pressures of some azides have been determined by the transpiration method. The molar enthalpies of vaporization of these compounds were derived from the temperature dependencies of vapor pressures. The measured data sets were successfully checked for internal consistency by comparison with vaporization enthalpies of similarly structured compounds.

Compounds

#	Formula	Name
1	C4H9N3O	(azidoethoxy)ethane
2	C2H5N3O	2-azidoethanol
3	C4H7N3O2	ethyl azidoacetate
4	C2H2N4	2-azidoacetonitrile
5	C7H7N3S	azidomethyl phenyl sulfide
6	C5H9N3	cyclopentyl azide
7	C6H11N3	azidocyclohexane
8	C7H12O2	cyclopentyl ethanoate

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Phase	Method	#Points
POMD	1	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	derived form transpriration measurements	1
POMD	1	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	22
POMD	2	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	derived from transpriration measurements	1
POMD	2	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	15
POMD	3	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	derived from transpriration measurements	1
POMD	3	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	11
POMD	4	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	derived from transpriration measurements	1
POMD	4	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	12
POMD	5	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	derived from tranpriration measurements	1
POMD	5	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	8
POMD	6	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	derived from transpiration measurements	1
POMD	6	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	28
POMD	7	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	derived from transpiration measurements	1
POMD	7	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	16
POMD	8	Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid	Temperature, K; Liquid	Liquid Gas	derived from tranpriration measurements	1
POMD	8	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	13

Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Vapor pressures and enthalpies of vaporization of azides

Verevkin, S. P.[Sergey P.], Emelyanenko, V. N.[Vladimir N.], Algarra, M.[Manuel], Lopez-romero, J. M., Aguiar, F.[Fabio], Rodriguez-Borges, J. E., Esteves Da Silva, J. C. G.[Joaquim C. G.]

ABSTRACT