Name: ThermoML Representation of Published Experimental Data from Journal of Chemical Thermodynamics (0021-9614, Elsevier)
Creator: Thermodynamics Research Center
License: https://www.nist.gov/open/license

ABSTRACT

Vapor pressures of the linear 1-(n-alkyl)-imidazoles with the alkyl chain C3, C5 C7, and C9 C10 have been measured by the transpiration method. The molar enthalpies of vaporization Dg l Hm of these compounds were derived from the temperature dependencies of vapor pressures. A linear correlation of enthalpies of vaporization Dgl Hm (298.15 K) of the 1-(n-alkyl)-imidazoles with the chain length has been found.

Compounds

#	Formula	Name
1	C6H10N2	1-propylimidazole
2	C8H14N2	1-pentylimidazole
3	C10H18N2	1-heptylimidazole
4	C12H22N2	1-nonylimidazole
5	C14H26N2	1-undecylimidazole
6	C9H16N2	1-hexylimidazole
7	C13H24N2	1-decylimidazole
8	C15H28N2	1-dodecyl-1H-imidazole

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Phase	Method	#Points
POMD	1	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	23
POMD	2	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	16
POMD	3	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	39
POMD	4	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	34
POMD	5	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	25
POMD	6	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	31
POMD	7	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	40
POMD	8	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	36

Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Building blocks for ionic liquids: Vapor pressures and vaporization enthalpies of 1-(n-alkyl)-imidazoles

Emel yanenko, V. N.[Vladimir N.], Portnova, S. V.[Svetlana V.], Verevkin, S. P.[Sergey P.], Skrzypczak, A.[Andrzej], Schubert, T. J. S.[Thomas J. S.]

ABSTRACT