Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Density and surface tension of pure 1-ethyl-3-methylimidazolium L-lactate ionic liquid and its binary mixtures with water

Wang, J.-y.[Jian-ying], Jiang, H.-C.[Hai-Chao], Liu, Y.-M.[Yu-Min], Hu, Y.-Q.[Yong-Qi]
J. Chem. Thermodyn. 2011, 43, 5, 800-804
ABSTRACT
The density and surface tension of 1-ethyl-3-methylimidazolium L-lactate ([emim][L-lactate]) ionic liquid were determined from T = (283.15 to 333.15) K. The coefficients of thermal expansion were calculated from the experimental density results using an empirical correlation for T = (283.15 to 333.15) K. Molecular volume and standard entropies of the IL were calculated from the experimental density values. The surface properties of IL were investigated. The critical temperature and enthalpy of vaporization were also discussed. Density and surface tension have been measured over the whole composition range for {[emim][L-lactate] + water} binary systems at a temperature of 298.15 K and atmospheric pressure. Excess molar volumes and the surface tension deviations have been determined.
Compounds
# Formula Name
1 C9H16N2O3 3-ethyl-1-methylimidazolium (S)-2-hydroxypropanoate
2 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • digital tensiometer
  • 10
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • densimeter (MYX-1)
  • 10
  • POMD
  • 2
  • 1
  • Surface tension liquid-gas, N/m ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • digital tensiometer
  • 22
  • POMD
  • 2
  • 1
  • Mass density, kg/m3 ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • densimeter (MYX-1)
  • 19
  • POMD
  • 2
  • 1
  • Excess molar volume, m3/mol ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Calculated with densities of this investigation
  • 19