ABSTRACT

Densities and speeds of sound of binary liquid mixtures of 1-nonanol with o-cresol, m-cresol, p-cresol and anisole have been measured over the entire range of composition at T = (293.15 and 313.15) K and at atmospheric pressure. Using these data, the excess molar volume, molar free volume, parameters related to space-filling ability, non-linearity parameters, isentropic compressibility, molar isentropic compressibility, deviation of molar isentropic compressibility, deviations of the speed of sound, and limiting excess partial molar volume, and isentropic compressibility, have been calculated. The calculated excess and deviation functions have been fitted to the Redlich-Kister polynomial equations and the results analyzed in terms of molecular interactions and structural effects.

Compounds

#	Formula	Name
1	C9H20O	nonan-1-ol
2	C7H8O	2-methylphenol
3	C7H8O	3-methylphenol
4	C7H8O	4-methylphenol
5	C7H8O	anisole

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	2 1	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Mole fraction - 2; Liquid	Pressure, kPa; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	32
POMD	2 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 2; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	32
POMD	3 1	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Mole fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	32
POMD	3 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	32
POMD	4 1	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Mole fraction - 4; Liquid	Pressure, kPa; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	32
POMD	4 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 4; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	32
POMD	5 1	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	32
POMD	5 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	32

Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Volumetric and ultrasonic behaviour of binary mixtures of 1-nonanol with o-cresol, m-cresol, p-cresol and anisole at T = (293.15 and 313.15) K

Bhatia, S. C.[Subhash C.], Rani, R.[Ruman], Bhatia, R.[Rachna], Anand, H.[Hardeep]

ABSTRACT