Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

ABSTRACT

This work reports the standard (p = 0.1 MPa) molar enthalpies of formation, in the gaseous phase, DfH mogP, of 2,4-, 2,6-, and 3,5-dibromophenol, at T = 298.15 K, respectively, as (59.6 +- 2.6) kJ mol 1, (49.1 +- 2.2) kJ mol 1 and (39.5 +- 2.0) kJ mol 1. These experimental values were derived from the measurements of the standard molar enthalpies of formation, in the crystalline phase, DfH mo2; 4-dibromophenol; crP 1/4 o140:9 2:1P kJ mol 1, DfH mo2; 6-dibromophenol; crP 1/4 o132:5 1:6P kJ mol 1 and DfH m o3; 5-dibromophenol; crP 1/4 o134:5 1:7P kJ mol 1, at the same reference temperature, achieved from the standard molar enthalpies of combustion, in oxygen, to yield CO2(g) and HBr 600H2O(l), measured by rotating-bomb combustion calorimetry, together with measurements of the standard molar enthalpies of sublimation, at T = 298.15 K, as Dg crH mo2; 4-dibromophenolP 1/4 o81:3 1:5P kJ mol 1, Dg crH mo2; 6-dibromophenolP 1/4 o83:4 1:5P kJ mol 1 and Dg crH mo3; 5-dibromophenolP 1/4 o94:3 1:8P kJ mol 1, obtained using the Calvet high temperature vacuum sublimation technique. The standard molar enthalpy of sublimation, at T = 298.15 K, for the 3,5-dibromophenol was also determined from the temperature vapour pressure dependence, obtained by the Knudsen mass loss effusion method, Dg crH mo3; 5-dibromophenolP 1/4 o95:0 1:1P kJ mol 1. For this isomer it is also reported the standard (p = 0.1 MPa) molar entropy and Gibbs energy of sublimation, at T = 298.15 K. The experimental values of the gas-phase enthalpies of formation of each compoundwere compared with estimates using the empirical scheme developed by Cox and with the calculated values based on density functional theory calculations using the B3LYP hybrid exchange-correlation energy functional at the 6-311++G(d,p) basis set. These two methodologies were also used to estimate the enthalpies of formation in the gas-phase of the 2,3-, 2,5-, and 3,4-dibromophenol.