Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

ABSTRACT

Mutual solubility data of imidazolium-based ionic liquid, 1-butyl-2,3-dimethylimidazolium tetrafluoroborate ([bmmim][BF4]) with the alcohols, 1-propanol, 2-propanol, 1-butanol, 1-pentanol, and 1-hexanol were obtained by a cloud point method. The upper critical solution temperatures of the ionic liquid and alcohol mixtures were determined from the mutual solubility data. The upper critical solution temperature of the binary mixtures gradually increased as the chain length of the alcohol increased. The mutual solubility data of binary systems ([bmmim][BF4] + alcohols) have been correlated by the original UNIQUAC model as well as the extended and modified form of the UNIQUAC model. The temperature dependence of the mutual solubility data could be represented in terms of the temperature dependence of the binary energy parameters obtained from the correlation. Additionally the influence of water contamination on the ionic liquid mixture was shown experimentally by adding pure water into the binary mixture ([bmmim][BF4] + 1-butanol).