Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Measurement and prediction of (solid + liquid) equilibrium for sulfur compounds with aliphatic hydrocarbons

Didaoui, S.[Saeda], Ait-Kaci, A.[Ahmed], Rogalski, M.[Marek]
J. Chem. Thermodyn. 2010, 42, 10, 1261-1264
ABSTRACT
(Solid + liquid) equilibrium (SLE) of thiophene or diethylsulfide with n-heptane, n-octane or n-dodecane mixtures was measured by a static method. All the systems under study are simple eutectic systems. The DISQUAC group contribution model is fairly successful in predicting SLE.
Compounds
# Formula Name
1 C4H4S thiophene
2 C12H26 dodecane
3 C4H10S 3-thiapentane
4 C8H18 octane
5 C7H16 heptane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Molar enthalpy of transition or fusion, kJ/mol ; Crystal
  • Crystal
  • Liquid
  • Gas
  • Adiabatic calorimetry
  • 1
  • POMD
  • 2
  • Molar enthalpy of transition or fusion, kJ/mol ; Crystal
  • Crystal
  • Liquid
  • Gas
  • Adiabatic calorimetry
  • 1
  • POMD
  • 3
  • Molar enthalpy of transition or fusion, kJ/mol ; Crystal
  • Crystal
  • Liquid
  • Gas
  • Adiabatic calorimetry
  • 1
  • POMD
  • 4
  • Molar enthalpy of transition or fusion, kJ/mol ; Crystal
  • Crystal
  • Liquid
  • Gas
  • Adiabatic calorimetry
  • 1
  • POMD
  • 5
  • Molar enthalpy of transition or fusion, kJ/mol ; Crystal
  • Crystal
  • Liquid
  • Gas
  • Adiabatic calorimetry
  • 1
  • POMD
  • 1
  • 5
  • Eutectic temperature, K ; Crystal - 1
  • Crystal - 1
  • Crystal - 5
  • Liquid
  • Air at 1 atmosphere
  • PHASDIA:
  • 1
  • POMD
  • 1
  • 5
  • Eutectic composition: mole fraction - 1 ; Crystal - 1
  • Crystal - 1
  • Crystal - 5
  • Liquid
  • Air at 1 atmosphere
  • PHASDIA:
  • 1
  • POMD
  • 1
  • 5
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 5
  • DTA
  • 1
  • POMD
  • 1
  • 5
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • DTA
  • 11
  • POMD
  • 1
  • 4
  • Eutectic temperature, K ; Crystal - 1
  • Crystal - 1
  • Crystal - 4
  • Liquid
  • Air at 1 atmosphere
  • PHASDIA:
  • 1
  • POMD
  • 1
  • 4
  • Eutectic composition: mole fraction - 1 ; Crystal - 1
  • Crystal - 1
  • Crystal - 4
  • Liquid
  • Air at 1 atmosphere
  • PHASDIA:
  • 1
  • POMD
  • 1
  • 4
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 4
  • DTA
  • 5
  • POMD
  • 1
  • 4
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • DTA
  • 8
  • POMD
  • 1
  • 2
  • Eutectic temperature, K ; Crystal - 1
  • Crystal - 1
  • Crystal - 2
  • Liquid
  • Air at 1 atmosphere
  • PHASDIA:
  • 1
  • POMD
  • 1
  • 2
  • Eutectic composition: mole fraction - 1 ; Crystal - 1
  • Crystal - 1
  • Crystal - 2
  • Liquid
  • Air at 1 atmosphere
  • PHASDIA:
  • 1
  • POMD
  • 1
  • 2
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • DTA
  • 8
  • POMD
  • 1
  • 2
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • DTA
  • 1
  • POMD
  • 4
  • 3
  • Eutectic temperature, K ; Crystal - 4
  • Crystal - 4
  • Crystal - 3
  • Liquid
  • Air at 1 atmosphere
  • PHASDIA:
  • 1
  • POMD
  • 4
  • 3
  • Eutectic composition: mole fraction - 3 ; Crystal - 4
  • Crystal - 4
  • Crystal - 3
  • Liquid
  • Air at 1 atmosphere
  • PHASDIA:
  • 1
  • POMD
  • 4
  • 3
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 4
  • DTA
  • 10
  • POMD
  • 4
  • 3
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 3
  • DTA
  • 1
  • POMD
  • 2
  • 3
  • Eutectic temperature, K ; Crystal - 2
  • Crystal - 2
  • Crystal - 3
  • Liquid
  • Air at 1 atmosphere
  • PHASDIA:
  • 1
  • POMD
  • 2
  • 3
  • Eutectic composition: mole fraction - 3 ; Crystal - 2
  • Crystal - 2
  • Crystal - 3
  • Liquid
  • Air at 1 atmosphere
  • PHASDIA::
  • 1
  • POMD
  • 2
  • 3
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • DTA
  • 11
  • POMD
  • 2
  • 3
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 3
  • DTA
  • 1