Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

ABSTRACT

As part of our systematic study on physicochemical characterization of ionic liquids, in this work, we report new measurements of electrolytic conductivity and molar heat capacity for aqueous solutions of two 1-ethyl-3-methylimidazolium-based ionic liquids, namely: 1-ethyl-3-methylimidazolium dicyanamide and 1-ethyl-3-methylimidazolium 2-(2-methoxyethoxy) ethylsulfate, at normal atmospheric condition and for temperatures up to 353.2 K. The electrolytic conductivity and molar heat capacity were measured by a commercial conductivity meter and a differential scanning calorimeter (DSC), respectively. The estimated experimental uncertainties for the electrolytic conductivity and molar heat capacity measurements were +-1 % and +-2 %, respectively. The property data are reported as functions of temperature and composition. A modified empirical equation from another researcher [1] was used to correlate the temperature and composition dependence of our electrolytic conductivity results. An excess molar heat capacity expression derived using a Redlich-Kister type equation was used to represent the temperature and composition dependence of the measured molar heat capacity and calculated excess molar heat capacity of the solvent systems considered. The correlations applied represent our measurements satisfactorily as shown by an acceptable overall average deviation of 6.4 % and 0.1 %, respectively, for electrolytic conductivity and molar heat capacity.