Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Density and speed of sound measurements of hexadecane

Outcalt, S.[Stephanie], Laesecke, A.[Arno], Fortin, T. J.[Tara J.]
J. Chem. Thermodyn. 2010, 42, 6, 700-706
ABSTRACT
The density and speed of sound of hexadecane have been measured with two instruments. Both instruments use the vibrating-tube method for measuring density. Ambient pressure (83 kPa) density and speed of sound were measured with a commercial instrument from T = (290.65 to 343.15) K. Adiabatic compressibilities are derived from the density and speed of sound data at ambient pressure. Compressed liquid density was measured in a second instrument and ranged from T = (310 to 470) K with pressures from (1 to 50) MPa. The overall relative expanded uncertainty of the compressed liquid density measurements is (0.10 to 0.13) % (k = 2). The overall relative expanded uncertainty (k = 2.3) of the speed of sound measurements is 0.2 % and that of the ambient pressure density measurements is approximately 0.04 % (k = 2.3). The ambient pressure and compressed liquid density measurements are correlated within 0.1 % with a modified Tait equation.
Compounds
# Formula Name
1 C16H34 hexadecane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Speed of sound, m/s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Single path-length method
  • 16
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 16
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 92