Name: ThermoML Representation of Published Experimental Data from Journal of Chemical Thermodynamics (0021-9614, Elsevier)
Creator: Thermodynamics Research Center
License: https://www.nist.gov/open/license

Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Excess enthalpies of binary and ternary mixtures containing dibutyl ether (DBE), 1-butanol, and heptane at T = 298.15 K and 313.15 K

Aguilar, F.[Fernando], Alaoui, F. E. M.[Fatima E. M.], Segovia, J. J.[Jose J.], Villamanan, M. A.[Miguel A.], Montero, E. A.[Eduardo A.]

J. Chem. Thermodyn. 2010, 42, 1, 28-37

ABSTRACT

Experimental excess molar enthalpies of the ternary systems {dibutyl ether (DBE) + 1-butanol + heptane} and the corresponding binary systems at T = 298.15 K and T = 313.15 K at atmospheric pressure are reported. A quasi-isothermal flow calorimeter has been used to make the measurements. All the binary and the ternary systems show endothermic character. The experimental data for the binary and ternary systems have been fitted using the Redlich Kister equation, the NRTL and UNIQUAC models. The values of the standard deviation indicate good agreement between the experimental results and those calculated from the equations.

Compounds

#	Formula	Name
1	C8H18O	dibutyl ether
2	C4H10O	butan-1-ol
3	C7H16	heptane

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	3 1	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Flow calorimetry	38
POMD	2 1	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Flow calorimetry	38
POMD	2 3	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Temperature, K; Liquid Mole fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid	Flow calorimetry	38
POMD	2 3 1	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Temperature, K; Liquid Mole fraction - 3; Liquid Mole fraction - 2; Liquid	Pressure, kPa; Liquid	Liquid	Flow calorimetry	72