Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Volumetric properties of the (tetrahydrofuran + water) and (tetra-n-butyl ammonium bromide + water) systems: Experimental measurements and correlations

Belandria, V.[Veronica], Mohammadi, A. H.[Amir H.], Richon, D.[Dominique]
J. Chem. Thermodyn. 2009, 41, 12, 1382-1386
ABSTRACT
In this communication, we report experimental density data for the binary mixtures of (water + tetrahydrofuran) and (water + tetra-n-butyl ammonium bromide) at atmospheric pressure and various temperatures. The densities were measured using an Anton PaarTM digital vibrating-tube densimeter. For the (tetrahydrofuran + water) system, excess molar volumes have been calculated using the experimental densities and correlated using the Redlich Kister equation. The Redlich Kister equation parameters have been adjusted on experimental results. The partial molar volumes and partial excess molar volumes at infinite dilution have also been calculated for each component. A simple density equation was finally applied to correlate the measured density of the (tetra-n-butyl ammonium bromide + water) system.
Compounds
# Formula Name
1 C4H8O tetrahydrofuran
2 C16H36BrN tetrabutylammonium bromide
3 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 90
  • POMD
  • 2
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 90