Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

(Vapour + liquid) equilibria of the {trifluoromethane (HFC-23) + propane} and {trifluoromethane (HFC-23) + n-butane} systems

Ju, M.[Mincheol], Yun, Y.[Yongju], Shin, M. S.[Moon Sam], Kim, H.[Hwayong]
J. Chem. Thermodyn. 2009, 41, 12, 1339-1342
ABSTRACT
Isothermal (vapour + liquid) equilibrium data were measured for the two systems, {trifluoromethane (HFC-23) + propane} and {trifluoromethane (HFC-23) + n-butane}, at temperatures ranging from 283.15 K to 313.15 K at 10 K intervals. These experiments were performed with a circulating-type apparatus and on-line gas chromatography. Experimental data were well correlated by the Peng Robinson equation of state using the Wong Sandler mixing rules and the NRTL model.
Compounds
# Formula Name
1 CHF3 trifluoromethane
2 C3H8 propane
3 C4H10 butane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 4
  • POMD
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 4
  • POMD
  • 3
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 4
  • POMD
  • 2
  • 1
  • Vapor or sublimation pressure, kPa ; Gas
  • Temperature, K; Gas
  • Mole fraction - 1; Liquid
  • Gas
  • Liquid
  • Closed cell (Static) method
  • 38
  • POMD
  • 2
  • 1
  • Mole fraction - 1 ; Gas
  • Temperature, K; Gas
  • Mole fraction - 1; Liquid
  • Gas
  • Liquid
  • Chromatography
  • 38
  • POMD
  • 1
  • 3
  • Vapor or sublimation pressure, kPa ; Gas
  • Temperature, K; Gas
  • Mole fraction - 1; Liquid
  • Gas
  • Liquid
  • Closed cell (Static) method
  • 43
  • POMD
  • 1
  • 3
  • Mole fraction - 1 ; Gas
  • Temperature, K; Gas
  • Mole fraction - 1; Liquid
  • Gas
  • Liquid
  • Chromatography
  • 43