Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

ABSTRACT

(Solid + liquid) equilibria (SLE) and (liquid + liquid) equilibria (LLE) for the binary systems: {ionic liquid (IL) N-butyl-4-methylpyridinium tosylate (p-toluenesulfonate) [BM4Py][TOS], or N-butyl-3- methylpyridinium tosylate [BM3Py][TOS], or N-hexyl-3-methylpyridinium tosylate [HM3Py][TOS], or N-butyl-4-methylpyridinium bis{(trifluoromethyl)sulfonyl}imide [BM4Py][NTf2], or 1,4-dimethylpyridinium tosylate [M1,4Py][TOS], or 2,4,6-collidine tosylate [M2,4,6Py][TOS], or 1-ethyl-3-methylimidazolium thiocyanate [EMIM][SCN], or 1-butyl-3-methylimidazolium thiocyanate [BMIM][SCN], or 1-hexyl-3- methylimidazolium thiocyanate [HMIM][SCN], or triethylsulphonium bis(trifluoromethylsulfonyl)imide [Et3S][NTf2] + thiophene} have been determined at ambient pressure. A dynamic method was used over a broad range of mole fractions and temperatures from (270 to 390) K. In the case of systems (pyridinium IL, or sulphonium IL + thiophene) the mutual immiscibility with an upper critical solution temperature (UCST) was detected at the very narrow and low mole fraction of the IL. For the binary systems containing (imidazolium thiocyanate IL + thiophene), the mutual immiscibility with the lower critical solution temperature (LCST) was detected at the higher mole fraction range of the IL. The basic thermal properties of the pure ILs, i.e. melting and glass-transition temperatures as well as the enthalpy of fusion have been measured using a differential scanning microcalorimetry technique (DSC). The well-known NRTL equation has been used to correlate experimental SLE/LLE data sets.