Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

The (p, q, T) properties and apparent molar volumes V/ of (ZnBr2 + C2H5OH)

Guliyev, T.[Tavakkul], Safarov, J.[Javid], Shahverdiyev, A.[Astan], Hassel, E.[Egon]
J. Chem. Thermodyn. 2009, 41, 10, 1162 (-1169)
ABSTRACT
The (p, q, T) properties and apparent molar volumes V/ of ZnBr2 in ethanol at temperatures (293.15 to 393.15) K and pressures up to p = 40 MPa are reported. The measurements were made with a recently developed vibration-tube densimeter. The system was calibrated using double-distilled water, methanol, ethanol, and aqueous NaCl solutions. The experiments were carried out at molalities of m = (0.05681, 0.16958, 0.30426, 0.43835, 0.93055, 1.49016, and 1.88723) mol kg 1 using zinc bromide. An empirical correlation for the density of (ZnBr2 + C2H5OH) with pressure, temperature, and molality has been derived. This equation of state was used to calculate other volumetric properties such as isothermal compressibility, isobaric thermal expansibility, the differences in specific heat capacities at constant pressures and volumes, apparent molar volumes of ZnBr2 in ethanol, and partial molar volumes of both components.
Compounds
# Formula Name
1 Br2Zn zinc bromide
2 C2H6O ethanol
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 1
  • Mass density, kg/m3 ; Liquid
  • Molality, mol/kg - 1; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Vibrating tube method
  • 441