Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Complementary vapor pressure data for 2-methyl-1-propanol and 3-methyl-1-butanol at a pressure range of (15 to 177) kPa

Bejarano, A.[Arturo], Quezada, N.[Nathalie], de la Fuente, J. C.[Juan C.]
J. Chem. Thermodyn. 2009, 41, 9, 1020-1024
ABSTRACT
The vapor pressure of pure 2-methyl-1-propanol and 3-methyl-1-butanol, components called congeners that are present in aroma of wine, pisco, and other alcoholic beverages, were measured with a dynamic recirculation apparatus at a pressure range of (15 to 177) kPa with an estimated uncertainty less than0.2%. The measurements were performed at temperature ranges of (337 to 392) K for 2-methyl-1-propanol and (358 to 422) K for 3-methyl-1-butanol. Data were correlated using a Wagner-type equation with standard deviations of 0.09 kPa for the vapor pressure of 2-methyl-1-propanol and 0.21 kPa for 3-methyl- 1-butanol. The experimental data and correlation were compared with data selected from the literature.
Compounds
# Formula Name
1 C4H10O 2-methyl-1-propanol
2 C5H12O 3-methylbutan-1-ol
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Recirculating still
  • 14
  • POMD
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Recirculating Still
  • 17