Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Standard state thermodynamic properties of aqueous cesium chloride using high dilution calorimetry up to 598.15 K

Djamali, E.[Essmaiil], Chen, K.[Keith], Cobble, J. W.[James W.]
J. Chem. Thermodyn. 2009, 41, 9, 992-999
ABSTRACT
In this communication we report the calorimetric data for the standard state enthalpies of solution of cesium chloride obtained from low concentrations, down to (10 3 m), integral heats of solution measurement up to temperature of 573.30 K and extrapolated to 598.15 K. From these data and the unified theory of electrolytes, the complete standard state thermodynamic properties (H 2; G 2; C p;2; V 2; o@V 2=@TPp; o@V 2=@pPT ) of aqueous cesium chloride were determined up to temperature of 598.15 K.
Compounds
# Formula Name
1 H2O water
2 ClCs cesium chloride
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 1
  • Molar enthalpy of solution, kJ/mol ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 2; Liquid
  • Liquid
  • Crystal - 2
  • solution calorimitry
  • 3
  • POMD
  • 2
  • 1
  • Molar enthalpy of solution, kJ/mol ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 2; Liquid
  • Liquid
  • Crystal - 2
  • solution calorimetry
  • 18