ABSTRACT

The standard (p = 0.1 MPa) molar enthalpies of combustion of 5-nitroindole and 5-nitroindoline, both in the solid phase, were measured at T = 298.15 K by static bomb calorimetry. Further, the standard molar enthalpies of sublimation, at T = 298.15 K, of these two indole derivatives were determined by Knudsen effusion technique. The combustion calorimetry results together with those from the Knudsen effusion technique, were used to derive the standard molar enthalpies of formation, at T = 298.15 K, in the gaseous phase.

Compounds

#	Formula	Name
1	CO2	carbon dioxide
2	N2	nitrogen
3	H2O	water
4	O2	oxygen
5	C8H6N2O2	5-nitroindole
6	C8H8N2O2	5-nitroindoline

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Phase	Method	#Points
POMD	5	Vapor or sublimation pressure, kPa ; Crystal	Temperature, K; Crystal	Crystal Gas	Calculated from knudsen effusion weight loss	32
POMD	6	Mass density, kg/m3 ; Crystal	Temperature, K; Crystal Pressure, kPa; Crystal	Crystal	mass and volume measurement	1
POMD	6	Vapor or sublimation pressure, kPa ; Crystal	Temperature, K; Crystal	Crystal Gas	Calculated from knudsen effusion weight loss	36
RXND	5 1 2 3 4	Specific internal energy of reaction at constant volume, J/g			Static bomb calorimetry	1
RXND	6 1 2 3 4	Specific internal energy of reaction at constant volume, J/g			Static bomb calorimetry	1

Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Experimental study on the thermochemistry of 5-nitroindole and 5-nitroindoline

Ribeiro da Silva, M. A. V.[Manuel A. V.], Cabral, J. I. T. A.[Joana I. T. A.]

ABSTRACT