Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

ABSTRACT

The standard (p = 0.1 MPa) molar energies of combustion of 2-furancarbonitrile, 2-acetylfuran, and 3-furaldehyde were measured by static bomb combustion calorimetry; the Calvet high-temperature microcalorimetry was used to measure the enthalpies of vaporization of these liquid compounds. The standard molar enthalpies of formation of the three compounds, in the gaseous phase, at T = 298.15 K, have been derived from the corresponding standard molar enthalpies of formation in the liquid phase and the standard molar enthalpies of phase transition, as (106.8 +- 1.1) kJ mol 1, (207.4 +- 1.3) kJ mol 1, and (151.9 +- 1.1) kJ mol 1, for 2-furancarbonitrile, 2-acetylfuran, and 3-furaldehyde, respectively. Standard molar enthalpies of formation are discussed in terms of the isomerization ortho meta. Enthalpic increment values of the introduction of the functional groups CN, CHO, and COCH3 were also compared with some other heterocycles; i.e. thiophene and pyridine.