Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

(Vapor + liquid) equilibrium data for (carbon dioxide + 1,1-difluoroethane) system at temperatures from (258 to 343) K and pressures up to about 8 MPa

Madani, H.[Hakim], Valtz, A.[Alain], Coquelet, C.[Christophe], Meniai, A. H.[Abdeslam Hassen], Richon, D.[Dominique]
J. Chem. Thermodyn. 2008, 40, 10, 1490-1494
ABSTRACT
Accurate thermo-physical data are of utmost interest for the development of new efficient refrigeration systems. Carbon dioxide (R744) and 1,1-difluoroethane (R152a) are addressed here. Isothermal (vapor + liquid) equilibrium data are reported herein for (R744 + R152a) binary system in the (258 343) K temperature range and in the (0.14 to 7.65) MPa pressure range. A reliable static-analytic method taking advantage of two online ROLSITM micro capillary samplers is used for all thermodynamic measurements. The data are correlated using our in-house ThermoSoft thermodynamic model using the Peng Robinson equation of state, the Mathias Copeman alpha function, the Wong Sandler mixing rules, and the NRTL model.
Compounds
# Formula Name
1 C2H4F2 1,1-difluoroethane
2 CO2 carbon dioxide
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • CCELL:UFactor:24
  • 26
  • POMD
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • CCELL:UFactor:12
  • 3
  • POMD
  • 1
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 2; Gas
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • CCELL:UFactor:16
  • 67
  • POMD
  • 1
  • 2
  • Mole fraction - 2 ; Liquid
  • Mole fraction - 2; Gas
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 67