Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

ABSTRACT

This paper reports measurements of densities for the binary systems of an ionic liquid and an alkanol at T = (298.15, 303.15, and 313.15) K. The IL is trioctylmethylammonium bis(trifluoromethylsulfonyl)imide [OMA]+[Tf2N]- and the alkanols are methanol, or ethanol, or 1-propanol. The speed of sound at T = 298.15 K for the same binary systems was also measured. The excess molar volumes and the isentropic compressibilities for the above systems were then calculated from the experimental densities and the speed of sound, respectively. Redlich Kister smoothing polynomial equation was used to fit the excess molar volume and the deviation in isentropic compressibility data. The partial molar volumes were determined from the Redlich Kister coefficients. For all the systems studied, the excess molar volumes have both negative and positive values, while the deviations in isentropic compressibility are negative over the entire composition range.