Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

ABSTRACT

Excess molar volumes (VE) and ultrasonic sound velocities at T = 303.15 K and ambient pressure have been measured as a function of composition for the binary liquid mixtures of dimethylsulphoxide (DMSO) with ketones. The ketones studied in the present investigation include ethyl methyl ketone (EMK), diethylketone (DEK), methyl propyl ketone (MPK), methyl isobutyl ketone (MIBK), and cyclohexanone (CH). The VE values were measured using a dilatometer and were positive over the entire mole fraction range for all systems except in the binary system DMSO with EMK where the VE exhibits an inversion in sign. The experimental VE values have been correlated using Redlich Kister and Hwang et al. equations. The ultrasonic sound velocities for the above systems have been measured with a single crystal interferometer at a frequency of 3 MHz. The sound velocity (u) data have been used to calculate isentropic compressibility (Ks) and deviation in isentropic compressibility (DKs) over the entire range of volume fraction. The sound velocity data have been predicted in terms of free length theory (FLT), collision factor theory (CFT), and Nomoto relation. The results reveal that all the theories gave a satisfactory estimate of the sound velocity. The deviations in values of isentropic compressibility (DKs) were negative over the entire range of volume fraction in all the binary liquid mixtures. The results are interpreted with respect to possible molecular interactions between components.