Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

(p,Vm,T) measurements of (cyclohexane + nonane) at temperatures from 298.15 K to 328.15 K and at pressures up to 40 MPa

Moravkova, L., Wagner, Z., Linek, J.
J. Chem. Thermodyn. 2007, 39, 12, 1637-1648
ABSTRACT
The densities and speeds of sound of (cyclohexane + nonane) were measured at four temperatures from 298.15 K to 328.15 K, and the respective values of excess volumes V E m and adiabatic compressibility were calculated. Thereafter, the densities for the last system were measured at elevated pressures (0.1 to 40) MPa at four temperatures over the range 298.15 K to 328.15 K with a high-pressure apparatus. The high-pressure density data were fitted to the Tait equation and the isothermal compressibilities were calculated with a novel procedure with the aid of this equation. The low- and high-pressure values of V E m calculated from the density data show that the deviations from ideal behaviour in the system decrease slightly as the temperature and pressure are raised. The V E m data were fitted to the fourthorder Redlich Kister equation, with the maximum likelihood principle being applied for the determination of the adjustable parameters.
Compounds
# Formula Name
1 C9H20 nonane
2 C6H12 cyclohexane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:4
  • 64
  • POMD
  • 2
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:4
  • 1011