ABSTRACT

Bubble point temperatures at 95.5 kPa, over the entire composition range, are measured for the binary mixtures of acetonitrile with acetyl acetone, anisole, bromobenzene, isopropyl alcohol, methyl tertiary butyl ether, and tetra ethoxy silane making use of a Swietoslawski type ebulliometer. The measured liquid phase composition versus bubble point temperature are found to be well represented by the Wilson model. Measured values of the liquid phase mole fraction versus bubble point temperature data are presented, along with the computed values of the vapor phase mole fractions and activity coefficients, and discussed.

Compounds

#	Formula	Name
1	C2H3N	acetonitrile
2	C5H8O2	2,4-pentanedione
3	C7H8O	anisole
4	C6H5Br	bromobenzene
5	C3H8O	propan-2-ol
6	C5H12O	2-methoxy-2-methylpropane
7	C8H20O4Si	tetraethoxysilane

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	VIBTUB:UFactor:12	1
POMD	1	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	EBULLIO:UFactor:8	2
POMD	2	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	2	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	EBULLIO:UFactor:8	1
POMD	3	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	3	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	EBULLIO:UFactor:8	1
POMD	4	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	4	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	EBULLIO:UFactor:8	1
POMD	5	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	5	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	EBULLIO:UFactor:8	1
POMD	6	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	6	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	EBULLIO:UFactor:8	1
POMD	7	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	7	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	7	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	EBULLIO:UFactor:8	1
POMD	1 2	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid Gas	EBULLIO:UFactor:8	16
POMD	1 3	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid Gas	EBULLIO:UFactor:8	16
POMD	1 4	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid Gas	EBULLIO:UFactor:8	16
POMD	5 1	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid Gas	EBULLIO:UFactor:8	16
POMD	1 6	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 6; Liquid	Pressure, kPa; Liquid	Liquid Gas	EBULLIO:UFactor:8	16
POMD	1 7	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid Gas	EBULLIO:UFactor:8	17

Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

(Vapor + liquid) equilibrium of the binary mixtures formed by acetonitrile with selected compounds at 95.5 kPa

Prasad, T. E. V.[T. E. Vittal], Kumar, R. K., Prasad, D. H. L.

ABSTRACT