Densities (q), speeds of sound (u), isentropic compressibilities (ks), refractive indices (nD), and surface tensions (r) of binary mixtures of methyl salicylate (MSL) with 1-pentanol (PEN) have been measured over the entire composition range at the temperatures of 278.15 K, 288.15 K, and 303.15 K. The excess molar volumes (VE), excess surface tensions (rE), deviations in speed of sound (Du), deviations in isentropic compressibility (Dks), and deviations in molar refraction (DR) have been calculated. The excess thermodynamic properties VE, rE, Du, Dks, and DR were fitted to the Redlich Kister polynomial equation and the Ak coefficients as well as the standard deviations (d) between the calculated and experimental values have been derived. The surface tension (r) values have been further used for the calculation of the surface entropy (SS) and the surface enthalpy (HS) per unit surface area. The lyophobicity (b) and the surface mole fraction oxS2 P of the surfactant component PEN have been also derived using the extended Langmuir model. The results provide information on the molecular interactions between the unlike molecules that take place at the surface and the bulk.
Compounds
#
Formula
Name
1
C5H10O
pentan-3-one
2
C40H56BN
tetrabutylammonium tetraphenylborate(1-)
Datasets
The table above is generated from the ThermoML associated json file (link above).
POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied;
the numbers refer to the table of compounds on the left.