ABSTRACT

Densities, viscosities, and ultrasonic velocities of binary mixtures of trichloromethane with methanol, ethanol, propan-1-ol, and butan-1-ol have been measured over the entire range of composition, at (298.15 and 308.15) K and at atmospheric pressure. From the experimental values of density, viscosity, and ultrasonic velocity, the excess molar volumes (VE), deviations in viscosity (Dg), and deviations in isentropic compressibility (Djs) have been calculated. The excess molar volumes, deviations in viscosity and deviations in isentropic compressibility have been fitted to the Redlich-Kister polynomial equation. The Jouyban-Acree model is used to correlate the experimental values of density, viscosity, and ultrasonic velocity.

Compounds

#	Formula	Name
1	CHCl3	trichloromethane
2	CH4O	methanol
3	C2H6O	ethanol
4	C3H8O	propan-1-ol
5	C4H10O	butan-1-ol

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	2
POMD	1	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	2
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM:UFactor:2	2
POMD	2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB::UFactor:2	2
POMD	2	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	2
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM::UFactor:2	2
POMD	3	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB::UFactor:2	2
POMD	3	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	2
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM::UFactor:2	2
POMD	4	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB::UFactor:2	2
POMD	4	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	2
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM::UFactor:2	2
POMD	5	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB::UFactor:2	2
POMD	5	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	2
POMD	5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM::UFactor:2	2
POMD	2 1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	42
POMD	2 1	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	42
POMD	2 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM:UFactor:2	42
POMD	3 1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	42
POMD	3 1	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	42
POMD	3 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM:UFactor:2	42
POMD	1 4	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	42
POMD	1 4	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	42
POMD	1 4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM:UFactor:2	42
POMD	1 5	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	42
POMD	1 5	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	42
POMD	1 5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	PYCNOM:UFactor:2	42

Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Densities, viscosities, and ultrasonic velocity studies of binary mixtures of trichloromethane with methanol, ethanol, propan-1-ol, and butan-1-ol at T=(298.15 and 308.15) K

Kadam, U. B.[Ujjan B.], Hiray, A. P.[Apoorva P.], Sawant, A. B.[Arun B.], Hasan, M.[Mehdi]

ABSTRACT