Volumetric properties of binary mixtures of ionic liquid 1-butyl-3-methylimidazolium octylsulfate with water or propanol in the temperature range of 278.15 K to 328.15 K
Orchilles, A. V., Gonzalez-Alfaro, V.[Vicenta], Miguel, P. J.[Pablo J.], Vercher, E.[Ernesto], Martinez-Andreu, A.[Antoni]
Densities of 1-butyl-3-methylimidazolium octylsulfate ([bmim][OcOSO3]) solutions in water and 1-propanol have been measured with an oscillating-tube densimeter at temperatures from 278.15 K to 328.15 K. From these densities, apparent molar volumes V/ of [bmim][OcOSO3] in both solvents have been calculated, and its dependence on the molality has been treated with the Redlich and Meyer equation. Debye Huckel limiting slopes for 1-propanol at working temperatures have been calculated, and apparent molar volumes of [bmim][OcOSO3] at infinite dilution V ?/ in both solvents have been evaluated. The partial molar volume at infinite dilution of [bmim][OcOSO3] in water is higher than in 1-propanol and augments when the temperature augments. On the other hand, the partial molar volume at infinite dilution of [bmim][OcOSO3] in 1-propanol decreases when the temperature augments.
Compounds
#
Formula
Name
1
C16H32N2O4S
1-butyl-3-methylimidazolium octyl sulfate
2
H2O
water
3
C3H8O
propan-1-ol
Datasets
The table above is generated from the ThermoML associated json file (link above).
POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied;
the numbers refer to the table of compounds on the left.