ABSTRACT

Density q, viscosity g, and refractive index nD, values for (tetradecane + benzene, + toluene, + chlorobenzene, + bromobenzene, + anisole) binary mixtures over the entire range of mole fraction have been measured at temperatures (298.15, 303.15, and 308.15) K at atmospheric pressure. The speed of sound u has been measured at T = 298.15 K only. Using these data, excess molar volume VE, deviations in viscosity Dg, Lorentz Lorenz molar refraction DR, speed of sound Du, and isentropic compressibility Dks have been calculated. These results have been fitted to the Redlich and Kister polynomial equation to estimate the binary interaction parameters and standard deviations. Excess molar volumes have exhibited both positive and negative trends in many mixtures, depending upon the nature of the second component of the mixture. For the (tetradecane + chlorobenzene) binary mixture, an incipient inversion has been observed. Calculated thermodynamic quantities have been discussed in terms of intermolecular interactions between mixing components.

Compounds

#	Formula	Name
1	C2H6O	ethanol
2	C3H8O	propan-1-ol
3	C3H8O	propan-2-ol
4	C4H10O	butan-1-ol
5	C5H12O	pentan-1-ol
6	C5H12O	3-methylbutan-1-ol
7	C9H12	1,3,5-trimethylbenzene

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	3
POMD	1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Schott-Gerate viscometer model AVS 350	3
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	3
POMD	2	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	3
POMD	2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Schott-Gerate viscometer model AVS 350	3
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	3
POMD	3	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	3
POMD	3	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Schott-Gerate viscometer model AVS 350	3
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	3
POMD	4	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	3
POMD	4	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Schott-Gerate viscometer model AVS 350	3
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	3
POMD	5	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	3
POMD	5	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Schott-Gerate viscometer model AVS 350	3
POMD	5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	3
POMD	6	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	3
POMD	6	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Schott-Gerate viscometer model AVS 350	3
POMD	6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	3
POMD	7	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	4
POMD	7	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Schott-Gerate viscometer model AVS 350	3
POMD	7	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	3
POMD	1 7	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	Schott-Gerate viscometer model AVS 350	33
POMD	1 7	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	33
POMD	1 7	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	33
POMD	2 7	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	Schott-Gerate viscometer model AVS 350	33
POMD	2 7	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	33
POMD	2 7	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	33
POMD	3 7	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	Schott-Gerate viscometer model AVS 350	33
POMD	3 7	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	33
POMD	3 7	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	33
POMD	4 7	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	Schott-Gerate viscometer model AVS 350	33
POMD	4 7	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	33
POMD	4 7	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	33
POMD	5 7	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	Schott-Gerate viscometer model AVS 350	33
POMD	5 7	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	33
POMD	5 7	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	33
POMD	7 6	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	Schott-Gerate viscometer model AVS 350	33
POMD	7 6	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	33
POMD	7 6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	33

Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Thermodynamic properties of (tetradecane + benzene, + toluene, + chlorobenzene, + bromobenzene, + anisole) binary mixtures at T = (298.15, 303.15, and 308.15) K

Mutalik, V.[Venkatesh], Manjeshwar, L. S.[Lata S.], Sairam, M.[Malladi], Aminabhavi, T. M. [Tejraj M.]

ABSTRACT