Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

ABSTRACT

The standard (p_ = 0.1 MPa) molar energies of combustion, DcU_m, for crystalline 1-nitronaphthalene and 9-nitroanthracene were determined, at the temperature 298.15 K, using a static bomb combustion calorimeter. For these compounds, the standard molar enthalpies of sublimation, Dg crH_m, at T = 298.15 K, were derived by the Clausius-Clapeyron equation, from the temperature dependence of the vapour pressures of these compounds, measured by the Knudsen effusion technique. These values were used to derive the standard molar enthalpies of formation of the compounds in their crystalline and gaseous phases, respectively. The derived standard molar enthalpies of formation, in the gaseous state, are analysed in terms of enthalpic increments and interpreted in terms of molecular structure. Using estimated values for the heat capacity differences between the gas and the crystal phases of the studied compounds, the standard (p_ = 0.1 MPa) molar enthalpies, entropies and Gibbs energies of sublimation, at T = 298.15 K, were derived. Additionally, standard enthalpies of formation for these two compounds were estimated by computations based on density functional theory. The estimated values are in excellent agreement with experimental data, which gives support to the estimates based on computational thermochemistry for the gas-phase enthalpies of formation of 2-nitronaphthalene, 1-nitroanthracene and 2-nitroanthracene.