ABSTRACT

The coexistence curves and turbidity data for a critical solution of (benzonitrile + hexadecane) have been reported. The critical amplitudes and exponents relating to the difference in density variables of two coexisting phases, the correlation length, and the osmotic compressibility have been calculated. The experimental results of the coexistence curves have also been analyzed to examine the Wegner correction terms and the behaviour of the diameter of the coexistence curves. A combination of the Wegner equation and the expression for the diameter has been used to describe successfully the coexistence curves.

Compounds

#	Formula	Name
1	C7H5N	benzonitrile
2	C16H34	hexadecane

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Refractive index (other wavelength) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid Wavelength, nm; Liquid	Liquid	Method described in references 3 and 4 of the article	6
POMD	2	Refractive index (other wavelength) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid Wavelength, nm; Liquid	Liquid	Method described in references 3 and 4 of the article	8
POMD	1 2	Refractive index (other wavelength) ; Liquid mixture 1	Temperature, K; Liquid mixture 1	Pressure, kPa; Liquid mixture 1 Wavelength, nm; Liquid mixture 1	Liquid mixture 1 Liquid mixture 2	Method described in references 3 and 4 of the article	31
POMD	1 2	Refractive index (other wavelength) ; Liquid mixture 2	Temperature, K; Liquid mixture 2	Pressure, kPa; Liquid mixture 2 Wavelength, nm; Liquid mixture 2	Liquid mixture 2 Liquid mixture 1	Method described in references 3 and 4 of the article	31
POMD	1 2	Upper consolute temperature, K ; Liquid mixture 1	Pressure, kPa; Liquid mixture 1		Liquid mixture 1 Liquid mixture 2	Derived from index of refraction measurments	1
POMD	1 2	Mole fraction - 1 ; Liquid mixture 1	Temperature, K; Liquid mixture 1	Pressure, kPa; Liquid mixture 1	Liquid mixture 1 Liquid mixture 2	Index of refraction calibration data	31
POMD	1 2	Mole fraction - 1 ; Liquid mixture 2	Temperature, K; Liquid mixture 2	Pressure, kPa; Liquid mixture 2	Liquid mixture 2 Liquid mixture 1	Index of refraction calibration data	31
POMD	1 2	Upper consolute composition: mole fraction - 1 ; Liquid mixture 1	Pressure, kPa; Liquid mixture 1		Liquid mixture 1 Liquid mixture 2	derived from index of refraction	1
POMD	1 2	Refractive index (other wavelength) ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid Wavelength, nm; Liquid	Liquid	Method described in references 3 and 4 of the article	67

Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

The measurements of coexistence curves and turbidity for {xC6H5CN + (1 - x)CH3(CH2)14CH3} in the critical region

Wang, N.[Nong], Mao, C.[Chunfeng], Xuhong, P.[Peng], An, X.[Xueqin], Shen, W.[Weiguo]

ABSTRACT