ABSTRACT

Physico-chemical properties viz., density, viscosity, and refractive index at temperatures = (298.15, 303.15, and 308.15) K and the speed of sound at T = 298.15 K are measured for the binary mixtures of methylcyclohexane with ethanol, propan1-ol, propan-2-ol, butan-1-ol, 2-methyl-1-propanol, and 3-methyl-1-butanol over the entire range of mixture composition. From these data, excess molar volume, deviations in viscosity, molar refraction, speed of sound, and isentropic compressibility have been calculated. These results are fitted to the polynomial equation to derive the coefficients and standard errors. The experimental and calculated quantities are used to study the nature of mixing behaviours between the mixture components.

Compounds

#	Formula	Name
1	C3H8O	propan-1-ol
2	C3H8O	propan-2-ol
3	C4H10O	butan-1-ol
4	C4H10O	2-methyl-1-propanol
5	C7H14	methylcyclohexane
6	C5H12O	3-methylbutan-1-ol
7	C2H6O	ethanol

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	ABBE::UFactor:4	3
POMD	1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB::UFactor:2	3
POMD	1	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Linear variable-path acoustic interferometer	1
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB::UFactor:4	3
POMD	2	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	ABBE::UFactor:4	3
POMD	2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB::UFactor:2	3
POMD	2	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Linear variable-path acoustic interferometer	1
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	3
POMD	3	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	ABBE::UFactor:8	3
POMD	3	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB::UFactor:2	3
POMD	3	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Linear variable-path acoustic interferometer	1
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB::UFactor:4	3
POMD	4	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	ABBE::UFactor:4	3
POMD	4	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB::UFactor:2	3
POMD	4	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Linear variable-path acoustic interferometer	1
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB::UFactor:4	3
POMD	5	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	ABBE:UFactor:4	3
POMD	5	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	3
POMD	5	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Linear variable-path acoustic interferometer	1
POMD	5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB::UFactor:4	3
POMD	6	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	ABBE::UFactor:4	3
POMD	6	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB::UFactor:2	3
POMD	6	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Linear variable-path acoustic interferometer	1
POMD	6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB::UFactor:4	3
POMD	7	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	ABBE::UFactor:4	3
POMD	7	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB::UFactor:2	3
POMD	7	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Linear variable-path acoustic interferometer	1
POMD	7	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB::UFactor:4	3
POMD	2 5	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	33
POMD	2 5	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	ABBE:UFactor:4	33
POMD	2 5	Speed of sound, m/s ; Liquid	Mole fraction - 5; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	11
POMD	2 5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	33
POMD	3 5	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	33
POMD	3 5	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	ABBE:UFactor:8	33
POMD	3 5	Speed of sound, m/s ; Liquid	Mole fraction - 5; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	11
POMD	3 5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	33
POMD	4 5	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	33
POMD	4 5	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	ABBE:UFactor:4	33
POMD	4 5	Speed of sound, m/s ; Liquid	Mole fraction - 5; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	11
POMD	4 5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	33
POMD	5 6	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	33
POMD	5 6	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	ABBE:UFactor:4	33
POMD	5 6	Speed of sound, m/s ; Liquid	Mole fraction - 5; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	11
POMD	5 6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	33
POMD	7 5	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	33
POMD	7 5	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	ABBE:UFactor:4	33
POMD	7 5	Speed of sound, m/s ; Liquid	Mole fraction - 5; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	11
POMD	7 5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	33
POMD	1 5	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:2	33
POMD	1 5	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	ABBE:UFactor:4	33
POMD	1 5	Speed of sound, m/s ; Liquid	Mole fraction - 5; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Linear variable-path acoustic interferometer	11
POMD	1 5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	33

Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Physico-chemical and excess properties of the binary mixtures of methylcyclohexane + ethanol, + propan-1-ol, + propan-2-ol, + butan-1-ol, + 2-methyl-1-propanol, or 3-methyl-1-butanol at T = (298.15, 303.15, and 308.15) K

Aralaguppi, M. I.[Mrityunjaya I.], Baragi, J. G.[Jagadish G.]

ABSTRACT