ABSTRACT

Excess molar volumes V E m and change in refractive indices Dmixn of the binary mixtures of (toluene + methanol), (toluene + ethanol), (toluene + 1-propanol), (toluene + iodoethane), (methanol + iodoethane), (ethanol + iodoethane), (1-propanol + iodoethane), and the ternary mixtures of (toluene + methanol + iodoethane), (toluene + ethanol + iodoethane), and (toluene + 1- propanol + iodoethane) were measured with vibrating-tube densimeters and an Abbe-type refractometer at the temperature 298.15 K and the pressure 101 kPa. The experimental V E m and Dmixn values of the ternary systems were predicted by empirical equations using binary solution data.

Compounds

#	Formula	Name
1	C7H8	toluene
2	CH4O	methanol
3	C2H6O	ethanol
4	C3H8O	propan-1-ol
5	C2H5I	iodoethane

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	ABBE:UFactor:4	1
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	2	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	ABBE:UFactor:4	1
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	3	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	ABBE:UFactor:4	1
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	4	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	ABBE:UFactor:4	1
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	5	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	ABBE:UFactor:4	1
POMD	5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	5 1	Refractive index (Na D-line) ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	ABBE:UFactor:8	14
POMD	5 1	Mass density, kg/m3 ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating tube method	14
POMD	2 5	Refractive index (Na D-line) ; Liquid	Mole fraction - 2; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	ABBE:UFactor:8	12
POMD	2 5	Mass density, kg/m3 ; Liquid	Mole fraction - 2; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating tube method	12
POMD	3 5	Refractive index (Na D-line) ; Liquid	Mole fraction - 3; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	ABBE:UFactor:8	11
POMD	3 5	Mass density, kg/m3 ; Liquid	Mole fraction - 3; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating tube method	11
POMD	4 5	Refractive index (Na D-line) ; Liquid	Mole fraction - 4; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	ABBE:UFactor:8	11
POMD	4 5	Mass density, kg/m3 ; Liquid	Mole fraction - 4; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating tube method	11
POMD	2 1	Refractive index (Na D-line) ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	ABBE:UFactor:8	13
POMD	2 1	Mass density, kg/m3 ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating tube method	13
POMD	3 1	Refractive index (Na D-line) ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	ABBE:UFactor:8	12
POMD	3 1	Mass density, kg/m3 ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating tube method	12
POMD	4 1	Refractive index (Na D-line) ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	ABBE:UFactor:8	12
POMD	4 1	Mass density, kg/m3 ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating tube method	12
POMD	2 5 1	Refractive index (Na D-line) ; Liquid	Mole fraction - 1; Liquid Mole fraction - 2; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	ABBE:UFactor:8	30
POMD	2 5 1	Mass density, kg/m3 ; Liquid	Mole fraction - 1; Liquid Mole fraction - 2; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating tube method	30
POMD	3 5 1	Refractive index (Na D-line) ; Liquid	Mole fraction - 1; Liquid Mole fraction - 3; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	ABBE:UFactor:8	30
POMD	3 5 1	Mass density, kg/m3 ; Liquid	Mole fraction - 1; Liquid Mole fraction - 3; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating tube method	30
POMD	4 5 1	Refractive index (Na D-line) ; Liquid	Mole fraction - 1; Liquid Mole fraction - 4; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	ABBE:UFactor:8	30
POMD	4 5 1	Mass density, kg/m3 ; Liquid	Mole fraction - 1; Liquid Mole fraction - 4; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating tube method	30

Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Experimental and predicted volumetric and refractive index properties of ternary mixtures of iodoethane with toluene and alcohols at temperature 298.15 K and pressure 101 kPa

Atik, Z.[Zadjia]

ABSTRACT