Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Partial molar volumes and partial molar adiabatic compressibilities of a short chain perfluorosurfactant: Sodium heptafluorobutyrate in aqueous solutions at different temperatures

Blanco, E.[Elena], Ruso, J. M.[Juan M.], Prieto, G.[Gerardo], Sarmiento, F.[Felix]
J. Chem. Thermodyn. 2005, 37, 12, 1351-1355
ABSTRACT
Density and ultrasound measurements of sodium heptafluorobutyrate in aqueous solutions at T = (283.15, 288.15, 293.15, 298.15, 303.15, 308.15, 313.15, 318.15, and 323.15) K have been obtained. From these results partial molar volumes and isentropic partial molar adiabatic compressibilities were calculated. Deviations from the Debye Huckel limiting law provide evidence for limited association at lower concentrations. The change of the partial molar volume and isentropic partial molar adiabatic compressibility upon aggregation was calculated. Variations of the change of partial molar volumes and isentropic partial molar adiabatic compressibility upon aggregation are discussed in terms of temperature.
Compounds
# Formula Name
1 C4F7NaO2 butanoic acid, heptafluoro-, sodium salt
2 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • Speed of sound, m/s ; Liquid
  • Molality, mol/kg - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • FPINT:UFactor:2
  • 162
  • POMD
  • 1
  • 2
  • Mass density, kg/m3 ; Liquid
  • Molality, mol/kg - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • VIBTUB:UFactor:16
  • 162