The standard (p? = 0.1 MPa) molar enthalpies of formation for crystalline 1-hydroxyisoquinoline, 5-hydroxyisoquinoline and 1,5-diidroxyisoquinoline, were derived from the standard molar enthalpies of combustion, in oxygen, at the temperature 298.15 K, measured by static bomb-combustion calorimetry. The standard molar enthalpies of sublimation at T = 298.15 K were determined by Calvet microcalorimetry The derived standard molar enthalpies of formation, in the gaseous state, are analysed in terms of enthalpic increments and interpreted in terms of molecular structure.
Compounds
#
Formula
Name
1
CO2
carbon dioxide
2
N2
nitrogen
3
H2O
water
4
O2
oxygen
5
C9H7NO
1-hydroxyisoquinoline
6
C9H7NO
5-hydroxyisoquinoline
7
C9H7NO2
1,5-dihydroxyisoquinoline
Datasets
The table above is generated from the ThermoML associated json file (link above).
POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied;
the numbers refer to the table of compounds on the left.
Type
Compound-#
Property
Variable
Constraint
Phase
Method
#Points
POMD
5
Molar enthalpy, kJ/mol ; Gas
Temperature, K; Gas
Pressure, kPa; Gas
Gas
drop microcalorimetry
1
POMD
6
Molar enthalpy, kJ/mol ; Gas
Temperature, K; Gas
Pressure, kPa; Gas
Gas
drop microcalorimetry
1
POMD
7
Molar enthalpy, kJ/mol ; Gas
Temperature, K; Gas
Pressure, kPa; Gas
Gas
drop microcalorimetry
1
RXND
5
1
2
3
4
Specific internal energy of reaction at constant volume, J/g
Static bomb calorimetry
1
RXND
6
1
2
3
4
Specific internal energy of reaction at constant volume, J/g
Static bomb calorimetry
1
RXND
7
1
2
3
4
Specific internal energy of reaction at constant volume, J/g