Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Volumetric properties of binary mixtures of alkoxyethanols with ethyl tert-butyl ether at various temperatures

Kinart, C. M.[Cezary M.], Nowak, K.[Katarzyna], Kinart, W. J.[Wojciech J.]
J. Chem. Thermodyn. 2005, 37, 5, 423-429
ABSTRACT
Densities at T = (293.15, 298.15, 303.15, 308.15, and 313.15) K in the binary liquid mixtures of ethyl tert-butyl ether with 2-methoxyethanol, 2-(2-methoxyethoxy)ethanol or 2-{2-(2-methoxyethoxy)ethoxy}ethanol have been measured over the entire mixture compositions. These data have been used to compute the excess molar volumes. The excess molar volumes are negative over the entire range of composition for all mixtures. The changes of VE with variations of the composition and the chain-length of the alkyl groups in the alkoxyethanol molecules are discussed in terms of intermolecular interactions.
Compounds
# Formula Name
1 C3H8O2 2-methoxyethan-1-ol
2 C5H12O3 2-(2-methoxyethoxy)ethanol
3 C7H16O4 2-[2-(2-methoxyethoxy)ethoxy]ethanol
4 C6H14O 2-ethoxy-2-methylpropane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • PYCNOM:UFactor:4
  • 5
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • PYCNOM:UFactor:4
  • 5
  • POMD
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • PYCNOM:UFactor:4
  • 5
  • POMD
  • 4
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • PYCNOM:UFactor:4
  • 5
  • POMD
  • 1
  • 4
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 4; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • PYCNOM:UFactor:4
  • 105
  • POMD
  • 2
  • 4
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 4; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • PYCNOM:UFactor:4
  • 105
  • POMD
  • 3
  • 4
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 4; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • PYCNOM:UFactor:4
  • 105