ABSTRACT

The isothermal and isobaric (vapuor + liquid) equilibria for (alpha-pinene + n-butanol + n-octane) at the temperatures T = 353.15 K, and 363.15 K, and at the pressure p = 53.33 kPa, measured with an inclined ebulliometer are presented. The measured ternary results are analyzed and compared with those calculated from the UNIQUAC equation with temperature-dependent binary parameters obtained from the binary literature data. The results shown the UNIQUAC equation can be used to predict these ternary data.

Compounds

#	Formula	Name
1	C10H16	2-pinene
2	C4H10O	butan-1-ol
3	C8H18	octane

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Normal boiling temperature, K ; Liquid			Liquid Gas	EBULLIO:UFactor:4:FP	1
POMD	1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	VIBTUB:mpointUFactor:4	1
POMD	2	Normal boiling temperature, K ; Liquid			Liquid Gas	EBULLIO:UFactor:4:FP	1
POMD	2	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	VIBTUB:mpoint:UFactor:4	1
POMD	3	Normal boiling temperature, K ; Liquid			Liquid Gas	EBULLIO:UFactor:4:FP	1
POMD	3	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	VIBTUB:mpoint:UFactor:4	1
POMD	2 1 3	Vapor or sublimation pressure, kPa ; Liquid	Mole fraction - 1; Liquid Mole fraction - 2; Liquid	Temperature, K; Liquid	Liquid Gas	EBULLIO:UFactor:4	20
POMD	2 1 3	Vapor or sublimation pressure, kPa ; Liquid	Mole fraction - 1; Liquid Mole fraction - 2; Liquid	Temperature, K; Liquid	Liquid Gas	EBULLIO:UFactor:4	20
POMD	2 1 3	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 1; Liquid Mole fraction - 2; Liquid	Pressure, kPa; Liquid	Liquid Gas	EBULLIO:UFactor:4	20

Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Isothermal and isobaric (vapour + liquid) equilibria of (alpha-pinene + n-butanol + n-octane)

Xu, Z., Li, H.[Haoran], Wang, C.[Congmin], Liang, W.[Wanchun], Han, S.[Shijun]

ABSTRACT