Name: ThermoML Representation of Published Experimental Data from Journal of Chemical Thermodynamics (0021-9614, Elsevier)
Creator: Thermodynamics Research Center
License: https://www.nist.gov/open/license

ABSTRACT

Vapour pressures and the molar enthalpies of vaporization of the linear aliphatic nitriles C7 - C17 have been determined by the transpiration method. Kovat`s indices of these Compounds were measured by capillary gas-chromatography. A linear correlation of enthalpies of vaporization at T = 298.15 K of the nitriles studied with the Kovats indices has been found.

Compounds

#	Formula	Name
1	C7H13N	heptanenitrile
2	C8H15N	octanenitrile
3	C9H17N	nonanenitrile
4	C10H19N	1-decanenitrile
5	C11H21N	1-decylcyanide
6	C12H23N	n-dodecanenitrile
7	C13H25N	dodecanecarbonitrile
8	C14H27N	tetradecanenitrile
9	C15H29N	1-tetradecyl cyanide
10	C17H33N	heptadecanenitrile
11	C16H31N	hexadecanenitrile

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Phase	Method	#Points
POMD	1	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	10
POMD	2	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	12
POMD	3	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	24
POMD	4	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	12
POMD	5	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	22
POMD	6	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	23
POMD	7	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	17
POMD	8	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	15
POMD	9	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	13
POMD	10	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	13
POMD	11	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Transpiration method	13

Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Vapor Pressures and Enthalpies of Vaporization of a Series of the Linear Aliphatic Nitriles.

Emel'yanenko, V. N., Verevkin, S. P.[Sergey P.], Koutek, B.[Bohumir], Doubsky, J.[Jan]

ABSTRACT