Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Viscosity of aqueous solutions of 2-methoxyethanol, 2-ethoxyethanol, and ethanolamine

Islam, M. N., Islam, M. M., Yeasmin, M. N.
J. Chem. Thermodyn. 2004, 36, 10, 889-893
ABSTRACT
Viscosity (g) of (water+2-methoxyethanol), (water+2-ethoxyethanol), and (water+ ethanolamine) were measured precisely at the temperatures (303.15, 308.15, 313.15, 318.15, and 323.15) K covering the whole composition range. The viscosity deviations (Dg) from linearity based on mole fraction were calculated from the viscosity data and fitted to the Redlich-Kister equation. The Dg values are positive over the entire range of composition for (water+2-methoxyethanol) and (water+2-ethoxyethanol). Dg exhibits maximum at x?0.30 for (water+2-methoxyethanol), and at x?0.28 for (water+2-ethoxyethanol). While Dg values for (water+ethanolamine) are slightly negative up to x?0.24 with minimum at x?0.11, then become more positive over the rest composition with maximum at x?0.72. The Dg values, in all the cases, decrease with the increase in temperature.
Compounds
# Formula Name
1 H2O water
2 C3H8O2 2-methoxyethan-1-ol
3 C4H10O2 2-ethoxyethan-1-ol
4 C2H7NO 2-aminoethan-1-ol
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • PYCNOM:UFactor:2
  • 1
  • POMD
  • 2
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Capillary tube (Ostwald; Ubbelohde) method
  • 1
  • POMD
  • 2
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:4
  • 6
  • POMD
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • PYCNOM:UFactor:2
  • 1
  • POMD
  • 3
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:4
  • 6
  • POMD
  • 4
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 1
  • POMD
  • 4
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:4
  • 6
  • POMD
  • 2
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:4
  • 55
  • POMD
  • 3
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:4
  • 55
  • POMD
  • 4
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 4; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:4
  • 55