Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Heat capacity and enthalpy of fusion of pyrimethanil laurate (C24H37N3O2)

Sun, X.H.[Xiao Hong], Liu, Y.F.[Yuan Fa], Tan, Z.-C.[Zhi-Cheng], Di, [You-Ying], Wang, H.-F.[Hui-Fang], Wang, M.-H.[Mei-Han]
J. Chem. Thermodyn. 2004, 36, 10, 895-899
ABSTRACT
Low-temperature heat capacities of pyrimethanil laurate (C24H37N3O2) were precisely measured with an automated adiabatic calorimeter over the temperature range between T = 78 K and T = 340 K. The sample was observed to melt at (321.52 +/- 0.04) K. The molar enthalpy and entropy of fusion as well as the chemical purity of the compound were determined to be (67244 +/- 11) J ? mol_1, (209.28 ? 0.02) J ? mol_1 ? K_1, (0.9943 +/- 0.0004) mass fraction, respectively. The extrapolated melting temperature for the absolutely pure compound obtained from fractional melting experiments was (322.264 +/- 0.006) K.
Compounds
# Formula Name
1 C24H37N3O2 4,6-dimethyl-N-phenylpyrimidin-2-amine dodecanoate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Molar enthalpy of transition or fusion, kJ/mol ; Crystal
  • Crystal
  • Liquid
  • Gas
  • ADIACA:UFactor:2
  • 1
  • POMD
  • 1
  • Triple point temperature, K ; Crystal
  • Crystal
  • Liquid
  • Gas
  • ADIACA:UFactor:2
  • 1
  • POMD
  • 1
  • Molar heat capacity at constant pressure, J/K/mol ; Crystal
  • Temperature, K; Crystal
  • Pressure, kPa; Crystal
  • Crystal
  • SMALLAD:UFactor:2
  • 111
  • POMD
  • 1
  • Molar heat capacity at constant pressure, J/K/mol ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • SMALLAD:UFactor:2
  • 10