ABSTRACT

Density measurements have been carried out at T = 298.15 K for the CsCl-monosaccharide (D-galactose, D-xylose and Darabinose)- water systems. The apparent molar volume of saccharides V in the ternary solutions, the corresponding infinite dilution apparent molar volume V, and the standard transfer volume DtV of saccharides from water to aqueous CsCl solutions have been determined. The McMillan-Mayer theory was employed to relate the excess thermodynamic functions to a series of interaction parameters to obtain the volumetric interaction parameters of CsCl with monosaccharide in water. These parameters are interpreted by the group additivity principle and the stereochemistry of these monosaccharide molecules.

Compounds

#	Formula	Name
1	ClCs	cesium chloride
2	C6H12O6	(+)-galactose
3	C5H10O5	D-xylose
4	C5H10O5	D-(-)-arabinose
5	H2O	water

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	2 5	Mass density, kg/m3 ; Liquid	Molality, mol/kg - 2; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	6
POMD	3 5	Mass density, kg/m3 ; Liquid	Molality, mol/kg - 3; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	VIBTUB::UFactor:4	6
POMD	5 4	Mass density, kg/m3 ; Liquid	Molality, mol/kg - 4; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	VIBTUB::UFactor:4	6
POMD	1 5	Mass density, kg/m3 ; Liquid	Molality, mol/kg - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	6
POMD	3 1 5	Mass density, kg/m3 ; Liquid	Molality, mol/kg - 3; Liquid Molality, mol/kg - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	36
POMD	1 5 4	Mass density, kg/m3 ; Liquid	Molality, mol/kg - 4; Liquid Molality, mol/kg - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	36
POMD	2 1 5	Mass density, kg/m3 ; Liquid	Molality, mol/kg - 2; Liquid Molality, mol/kg - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	36

Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Volumetric properties and volumetric interaction parameters for the CsCl-monosaccharide (D-galactose, D-xylose and D-arabinose)-water systems at T = 298.15 K

Jiang, Y.[Yucheng], Hu, M.[Mancheng], Wang, J.[Jianji], Zhuo, K.[Kelei], Xia, S.[Shuquian]

ABSTRACT