Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

High-energy components of "designer gasoline and designer diesel fuel" I. Heat capacities, enthalpy increments, vapor pressures, critical properties, and derived thermodynamic functions for bicyclopentyl between the T=(10 and 600) K

Chirico, R. D.[Robert D.], Steele, W. V.[William V.]
J. Chem. Thermodyn. 2004, 36, 8, 633-643
ABSTRACT
Measurements leading to the calculation of the standard thermodynamic properties for gaseous bicyclopentyl (Chemicals Abstracts registry number [1636-39-1]) are reported. Experimental methods include adiabatic heat-capacity calorimetry, comparative ebulliometry, and differential-scanning calorimetry (d.s.c.). The critical temperature was determined by d.s.c. and the critical pressure and critical density were estimated. Standard molar entropies, standard molar enthalpies, and standard molar Gibbs free energies of formation are reported at selected temperatures between T=(298.15 and 600) K. Formation properties were calculated with a literature value for the enthalpy of combustion in the liquid phase. All results are compared with available literature values.
Compounds
# Formula Name
1 C10H18 1,1'-bicyclopentyl
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Molar enthalpy of transition or fusion, kJ/mol ; Crystal 1
  • Crystal 1
  • Liquid
  • Gas
  • Adiabatic calorimetry
  • 1
  • POMD
  • 1
  • Molar enthalpy of transition or fusion, kJ/mol ; Crystal 2
  • Crystal 2
  • Crystal 1
  • Gas
  • Adiabatic calorimetry
  • 1
  • POMD
  • 1
  • Molar enthalpy of transition or fusion, kJ/mol ; Crystal 3
  • Crystal 3
  • Crystal 2
  • Gas
  • Adiabatic calorimetry
  • 1
  • POMD
  • 1
  • Triple point temperature, K ; Crystal 1
  • Crystal 1
  • Liquid
  • Gas
  • Adiabatic calorimetry
  • 1
  • POMD
  • 1
  • Triple point temperature, K ; Crystal 2
  • Crystal 2
  • Crystal 1
  • Gas
  • Adiabatic calorimetry
  • 1
  • POMD
  • 1
  • Triple point temperature, K ; Crystal 3
  • Crystal 3
  • Crystal 2
  • Gas
  • Adiabatic calorimetry
  • 1
  • POMD
  • 1
  • Critical temperature, K ; Liquid
  • Liquid
  • Gas
  • DTA
  • 1
  • POMD
  • 1
  • Molar heat capacity at saturation pressure, J/K/mol ; Crystal 3
  • Temperature, K; Crystal 3
  • Crystal 3
  • Gas
  • Vacuum adiabatic calorimetry
  • 42
  • POMD
  • 1
  • Molar heat capacity at saturation pressure, J/K/mol ; Crystal 2
  • Temperature, K; Crystal 2
  • Crystal 2
  • Gas
  • Vacuum adiabatic calorimetry
  • 12
  • POMD
  • 1
  • Molar heat capacity at saturation pressure, J/K/mol ; Crystal 1
  • Temperature, K; Crystal 1
  • Crystal 1
  • Gas
  • Vacuum adiabatic calorimetry
  • 13
  • POMD
  • 1
  • Molar heat capacity at saturation pressure, J/K/mol ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Vacuum adiabatic calorimetry
  • 20
  • POMD
  • 1
  • Molar heat capacity at saturation pressure, J/K/mol ; Crystal 3
  • Temperature, K; Crystal 3
  • Crystal 3
  • Gas
  • Vacuum adiabatic calorimetry
  • 13
  • POMD
  • 1
  • Molar heat capacity at saturation pressure, J/K/mol ; Crystal 1
  • Temperature, K; Crystal 1
  • Crystal 1
  • Gas
  • Vacuum adiabatic calorimetry
  • 7
  • POMD
  • 1
  • Molar heat capacity at saturation pressure, J/K/mol ; Crystal 1
  • Temperature, K; Crystal 1
  • Crystal 1
  • Gas
  • Vacuum adiabatic calorimetry
  • 8
  • POMD
  • 1
  • Molar heat capacity at saturation pressure, J/K/mol ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Vacuum adiabatic calorimetry
  • 14
  • POMD
  • 1
  • Molar heat capacity at saturation pressure, J/K/mol ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • SDSC:UFactor:0.5
  • 10
  • POMD
  • 1
  • Molar enthalpy function {Hm(T)-Hm(0)}/T, J/K/mol ; Crystal 3
  • Temperature, K; Crystal 3
  • Crystal 3
  • Gas
  • Vacuum adiabatic calorimetry
  • 13
  • POMD
  • 1
  • Molar enthalpy function {Hm(T)-Hm(0)}/T, J/K/mol ; Crystal 2
  • Temperature, K; Crystal 2
  • Crystal 2
  • Gas
  • Vacuum adiabatic calorimetry
  • 7
  • POMD
  • 1
  • Molar enthalpy function {Hm(T)-Hm(0)}/T, J/K/mol ; Crystal 1
  • Temperature, K; Crystal 1
  • Crystal 1
  • Gas
  • Vacuum adiabatic calorimetry
  • 8
  • POMD
  • 1
  • Molar enthalpy function {Hm(T)-Hm(0)}/T, J/K/mol ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Vacuum adiabatic calorimetry
  • 14
  • POMD
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Twin ebulliometer
  • 22
  • POMD
  • 1
  • Molar entropy, J/K/mol ; Crystal 3
  • Temperature, K; Crystal 3
  • Crystal 3
  • Gas
  • Vacuum adiabatic calorimetry
  • 13
  • POMD
  • 1
  • Molar entropy, J/K/mol ; Crystal 2
  • Temperature, K; Crystal 2
  • Crystal 2
  • Gas
  • Vacuum adiabatic calorimetry
  • 7
  • POMD
  • 1
  • Molar entropy, J/K/mol ; Crystal 1
  • Temperature, K; Crystal 1
  • Crystal 1
  • Gas
  • Vacuum adiabatic calorimetry
  • 8
  • POMD
  • 1
  • Molar entropy, J/K/mol ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Vacuum adiabatic calorimetry
  • 14
  • POMD
  • 1
  • Mass density, kg/m3 ; Gas
  • Temperature, K; Gas
  • Gas
  • Liquid
  • OTHER
  • 3
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • OTHER
  • 3