Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

Isothermal (vapour + liquid) equilibrium at several temperatures of (1-chlorobutane + 1-octanol, or 1-decanol)

Garriga, R., Martinez, S., Perez, P., Gracia, M.
J. Chem. Thermodyn. 2004, 36, 1, 59-69
ABSTRACT
Vapour pressures of (1-chlorobutane + 1-octanol or 1-decanol) at several temperatures between T = 278:15 K and T = 323:15 K were measured by a static method. The reduction of the vapour pressures to obtain activity coe.cients and excess molar Gibbs free energies was carried out by .tting the vapour pressure data to the Wilson equation according to Barker's method. A description of the experimental behaviour according to the ERAS-model is presented.
Compounds
# Formula Name
1 C4H9Cl 1-chlorobutane
2 C8H18O octan-1-ol
3 C10H22O decan-1-ol
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • CCELL:UFactor:2
  • 10
  • POMD
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • CCELL:UFactor:2
  • 7
  • POMD
  • 3
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • CCELL:UFactor:2
  • 3
  • POMD
  • 1
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 2; Liquid
  • Liquid
  • Gas
  • CCELL:UFactor:2
  • 100
  • POMD
  • 1
  • 3
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 3; Liquid
  • Liquid
  • Gas
  • CCELL:UFactor:2
  • 99