Thermodynamics Research Center / ThermoML | Journal of Chemical Thermodynamics

(p, Vm, T, x) measurements for aqueous LiNO3 solutions

Abdulagatov, I. M., Azizov, N. D.
J. Chem. Thermodyn. 2004, 36, 1, 17-27
ABSTRACT
(p; Vm; T ; x) properties of four aqueous LiNO3 solutions (0.181, 0.526, 0.963, and 1.728) mol * kg^-1 H2O were measured in the liquid phase with a constant-volume piezometer immersed in a precision liquid thermostat. Measurements were made for 10 isotherms between (298 and 573) K. The range of pressure was from (2 to 40) MPa. The total uncertainty of density, pressure, temperature, and concentration measurements were estimated to be less than 0.06 %, 0.05 %, 10 mK, and 0.014 %, respectively. The values of saturated density were determined by extrapolating experimental (p; q) data to the vapor-pressure at .xed temperature and composition using an interpolating equation. A polynomial type of equation of state for speci.c volume was obtained as a function of temperature, pressure, and composition by a least-squares method from the experimental data. The average absolute deviation (AAD) between measured and calculated values from this polynomial equation for density was 0.02 %. Measured values of solution density were compared with values calculated from Pitzer's ion-interaction equation. The agreement is within (0.2 to 0.4) % depending of concentration range. 2003 Elsevier Ltd. All rights reserved.
Compounds
# Formula Name
1 H2O water
2 LiNO3 lithium nitrate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Molality, mol/kg - 2; Liquid
  • Liquid
  • PIESOM
  • 195