Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Experimental investigation and modeling of thermophysical properties of ethyl decanoate at high temperatures

Zhang, Y.[Ying], Zhan, T.[Taotao], Chen, J.[Junshuai], Liu, X.[Xiangyang], He, M.[Maogang]
Fluid Phase Equilib. 2019, 501, 112274
ABSTRACT
The use of ethyl decanoate combined with conventional diesel or biodiesel could be economically attractive. Thermophysical properties of ethyl decanoate at high temperatures can be an essential guidance for the structural design and optimization of the fuel injection system in diesel engine. The measurements of the speed of sound and the thermal diffusivity of ethyl decanoate (EeC10: 0) were carried out by the light scattering method, which are along five isobaric lines from (0.1 - 10) MPa at the temperatures (300.71 - 562.07) K and (295.34 - 565.49) K, respectively. The expanded relative uncertainties (k = 2) are estimated to be 1.2% for speed of sound and 2.4% for thermal diffusivity. The thermal conductivities of ethyl decanoate at pressures up to 10 MPa and in the temperature range (303 - 363) K are derived, which agree well with literature values finding an AAD of 0.81%. The pRhoT dependences of the thermal conductivity are analyzed based on the vibrational theory. The results obtained show that the higher density of biofuels leads to smaller distances between oscillating molecules, of which the collision probability and intermolecular energy transport are enhanced. The consistent behaviors of biofuels that higher density leads to higher conductivity, and the dependence of the thermal conductivity on density becomes smaller with temperature increase are verified.
Compounds
# Formula Name
1 C12H24O2 ethyl decanoate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Speed of sound, m/s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Brillouin light scattering
  • 127
  • POMD
  • 1
  • Thermal diffusivity, m2/s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Dynamic light scattering
  • 93