Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Experimental measurements and modelling of carbon dioxide solubility in aqueous AMP/MDEA and Piperazine/MDEA blends

Suleman, H.[Humbul], Maulud, A. S.[Abdulhalim Shah], Man, Z.[Zakaria]
Fluid Phase Equilib. 2018, 463, 142-148
ABSTRACT
Experimental measurements and modelling of carbon dioxide solubility were performed in separate aqueous blends of 2-amino-2-methyl-1-propanol (AMP)/N-methyldiethanolamine (MDEA) and piperazine (PZ)/MDEA in the high gas loading region. The experimental loadings of carbon dioxide were measured at various parametric values of pressure (102.5 to 4110)) kPa, temperature (303.15 to 343.15) K and solvent concentration (1 + 1 and 2 + 2 M). It is shown that addition of AMP and PZ to MDEA improved the overall carbon dioxide loadings and were in excellent agreement with the experimental values found in open literature. The experimental results were accurately correlated by a hybrid Kent-Eisenberg model, with an average deviation of 10.5%. Furthermore, the model satisfactorily estimated the carbon dioxide solubilities in AMP/MDEA and PZ/MDEA blends at other parametric conditions.
Compounds
# Formula Name
1 H2O water
2 C5H13NO2 N-methyldiethanolamine
3 C4H10N2 piperazine
4 CO2 carbon dioxide
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • 4
  • Mole fraction - 4 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Solvent: Mass fraction - 2; Liquid
  • Liquid
  • Gas
  • Phase equilibration
  • 4
  • POMD
  • 1
  • 3
  • 4
  • Mole fraction - 4 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Solvent: Mass fraction - 3; Liquid
  • Liquid
  • Gas
  • Phase equilibration
  • 4